Re-publication of an article by Mario A. Rosé on Agronotizie
Optimally manage a biogas plant it means becoming a "breeder of bacteria".
Like farm animals, i battery they do their best if they are kept in conditions that are optimal for them, it is therefore essential to monitor the various aspects that affect the functioning of the entire anaerobic system. It is known to all that the different manufacturers and some independent workshops, offer biological care service.
Typically all of these services have a weakness: the results are not provided in real time. Moreover, the analyzes provided, generally they only concern the dynamics of the anaerobic degradation process, but not the verification of the biomass quality – silage or by-products that are – with which the system is powered.
Some plant managers have equipped themselves with simple tools such as the pHmetro or the automatic titrator (called FOS / TAC in the lingo) and the results are often disappointing e, in some cases, even disastrous.
This table clarifies why:
|pH||Almost nothing. When there are significant changes in pH, it is generally too late and the plant is collapsing.||pHmetro|
|FOS / TAC||Poor. The guidelines apply to single tank systems fed with cow manure and corn. If other matrices or their mixtures are used, the "canonical" values are no longer valid. In plants a 2 or more tanks, it would take a specific FOS / TAC table for each stage of digestion. The tool does not provide any a priori assessment on the quality of biomass or manure, only an indirect indication of the state of the bacterial system (when it can sometimes be too late).||Automatic titrator or pH meter and burettes for manual titration|
|Biomethanization efficiency of the plant||High, as it indicates the % of degradation of the silage achieved by the process||Muffle furnace and thermobalance or precision balance|
|Dry matter of biomass||Media. By only detecting the dry matter, only a rough indication of the biomass quality is obtained. Two different batches of biomass, the parity of SS, they can make more or less methane.||Thermobalance or precision scale and oven|
|Volatile solids of biomass||High. SV content provides a’ more reliable indication of the methanogenic potential of a biomass, however, it is not a definitive figure.||Muffle furnace and thermobalance or precision balance|
|Residual methane potential of the digestate||Very high. Provides an indication of the unused fraction of the silage or feed biomass.||Laboratory batch reactor and measurement system for the volumes of gas produced by fermentation|
|BMP (Methanigen potential) of biomass||Very high. Provides an indisputable indication of the actual yield that can be expected from a batch of silage or other biomass, allowing to evaluate if the price of the same is appropriate. When using biomass mixtures, the BMP test allows to evaluate any inhibitory or synergistic effects.||Laboratory batch reactor and measurement system for the volumes of gas produced by fermentation|
|Complete degradation curve of biomass||Very high. Allows you to program the digester feeding and establish the optimal retention time of solids for each substrate or mixture of them. The ultimate value of the curve, For definition, is the BMP.||Laboratory batch reactor and measurement system for the volumes of gas produced by fermentation|
|Hydrolytic activity of the inoculum||Very high. It allows you to predict biological problems in time, or diagnose them more accurately when they happen.||Laboratory batch reactor and measurement system for the volumes of gases produced by fermentation and reference matrices.|
|Substrate inhibition||Very high. It allows you to measure the maximum amount of a given substrate that can be fed into the digester without causing problems. This test is particularly suitable when using "problematic" substrates (manure of animals treated with antibiotics, pollina, likely, remains of slaughter…)||Laboratory batch reactor and measurement system for the volumes of gas produced by fermentation|
|High school (specific methane activity)||Very high. Together with the hydrolytic activity test, allows you to measure the actual bacterial activity of the inoculum and therefore the health of the digester.||Batch laboratory batch reactor and measurement system for the volumes of gas produced by fermentation|
|Effectiveness of additives (probiotics, enzymes, etc.)||Very high. Additives are usually expensive, but their effectiveness is more often than not magnified by the sellers. Some even have unwanted effects: increase the amount of gas produced, but they lower the methane content.||At least 2 laboratory batch reactors with relative system for measuring the volumes of gas produced by fermentation|
|Small-scale simulation of the process, accelerated start-up strategies of the plant||Very high. During the start-up phase of the system, it allows you to save over 50% of the diesel fuel required for initial heating. In operation, allows you to optimize feeding strategies, of agitation, of recirculation between tanks, optimal working temperature, etc.||Continuous laboratory reactor kit, gas flow measurement system and data logging system with specific software|
How can we see, the minimum tools to be equipped in order to preventively monitor the biogas plant without leaving anything to chance, I'm a termobilancia The precision balance, a muffle furnace it's a reactor system(i) batch and meter(i) of the volume of gas produced over time.
A mini-laboratory configured in this way, it allows to carry out tests on a small scale, so as not to risk productivity losses caused by the "table" management of the plant.
Like all techniques, the measurement of the various parameters useful for managing a biogas plant requires a minimum of learning and a little’ of attention following the procedures correctly.
Generally, with 8 hours of theoretical training and some’ of practice, more than satisfactory results can be obtained.
Investments in equipment fluctuate from 3.200 € for a basic kit with good precision but manual reading, up to 16.000 € for a mini-workshop with 6 batch reactors, gas volume measurement with ± 1% margin of error and automatic data management.
There are even more powerful systems, but generally exceed the actual needs of the biogas plant manager, as they are designed for academic research or for the development or improvement of technologies by plant manufacturers.